3 edition of Transition metal complexes of phosphorus, arsenic and antimony ligands. found in the catalog.
Transition metal complexes of phosphorus, arsenic and antimony ligands.
C. A. McAuliffe
Bibliography: p. -389.
|Series||Aspects of inorganic chemistry|
|LC Classifications||QD181.P1 M2 1973b|
|The Physical Object|
|Pagination||xix, 428 p.|
|Number of Pages||428|
|LC Control Number||73177885|
Multiply bonded systems with low coordination number (one to three) involving phosphorus and its homologues, whether isolable or generated in situ at a metal complex, are versatile ligands that can function as two‐, four‐, six‐ or eight‐electron donors to transition metal fragments and that may be coordinated in η 1 (terminal), η 2 (side‐on), edge‐ or face‐bridging by: electron density at the transition metal, then the carbonyl chemical shift should reflect the electronic effects of ligands introduced into these complexes. Since the electron density at the metal in LNi(C0)3 complexes should increase as the CT basicity of L increases and decrease as the a acidity in-.
Inorganic metallocenes: The structures and aromaticity of sandwich compounds of the transition elements with inorganic rings. Coordination Chemistry Reviews , (), DOI: / Kensuke Naka, Yoshiki Chujo. Organo-Arsenic, Phosphorus, and Antimony Conjugated by: Organometallic chemistry is an interdisciplinary science which continues to grow at a rapid pace. Although there is continued interest in synthetic and structural studies the last decade has seen a growing interest in the potential of organometallic chemistry to provide answers to problems in catalysis synthetic organic chemistry and also in the development of new materials.
However, the organoelement compounds of phosphorus, arsenic and antimony find usefulness as ligands in transition metal chemistry due to their σ-donor and π-acceptor abilities which can be readily tuned by simply changing the substituents. The N-heterocyclic carbene (NHC) functionalized phosphinidene complexes [(pCy)(IiPr2Me2)Ru═PMes*] (4), [(pCy)(IiPr2Me2)Os═PMes*] (6), and [(Cp*)(IiPr2Me2)Rh═PMes*] (7) were generated by a double-dehydrohalogenation−ligation sequence of the corresponding primary phosphine complexes with 3 equiv of NHC. The effect of the NHC ligand on the electronic properties .
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Transition Metal Complexes of Phosphorus, Arsenic and Antimony Ligands. Editors (view affiliations) C. McAuliffe Transition Metal Complexes Containing Monotertiary Arsines and Stibines Pages Back Matter. Pages PDF. About this book. Keywords. metals phosphorus transition metal.
Editors and affiliations. Buy Transition metal complexes of phosphorus, arsenic and antimony ligands (Aspects of inorganic chemistry) on FREE SHIPPING on qualified ordersCited by: Transition metal complexes of antimony centered ligands based upon acenaphthyl scaffolds.
Coordination non-innocent or not. Sinas Furan, a Emanuel Hupf, ab Julian Boidol, a Julian Brünig, a Enno Lork, a Stefan Mebs * c and Jens Beckmann * aAuthor: Sinas Furan, Emanuel Hupf, Emanuel Hupf, Julian Boidol, Julian Brünig, Enno Lork, stephan mebs, Jens.
Get this from a library. Transition metal complexes of phosphorus, arsenic and antimony ligands. [C A McAuliffe]. Additional Physical Format: Online version: McAuliffe, C.A. (Charles Andrew), Transition metal complexes of phosphorus, arsenic and antimony ligands. Alyea E.C.
() Metal Complexes with Ditertiary Arsines. In: McAuliffe C.A. (eds) Transition Metal Complexes of Phosphorus, Arsenic and Antimony Ligands. Aspects of Inorganic by: 1. Part of the Aspects of Inorganic Chemistry book series Abstract Sincewhen Hofmann reported 1 the first phosphine† complexes (those formed between triethylphosphine and platinum and gold), the chemistry of the coordination complexes of transition metal ions and phosphines has been increasingly investigated; there are few fields of chemistry in which research activity increases at such Cited by: 5.
A Fourier transform carbon NMR study of the electronic effects of phosphorus, arsenic, and antimony ligands in transition-metal arsenic and antimony ligands. book complexes George M. Bodner Melanie P. MayCited by: Pidcock A.
() Group VB to Transition Metal Bonds. In: McAuliffe C.A. (eds) Transition Metal Complexes of Phosphorus, Arsenic and Antimony Ligands. Aspects of Inorganic by: 4. Reactions of hybrid oxygen-arsenic ligands:o-R 2 As-C 6 H 4 CO 2 H (R = Me, Et, C 6 H 11, Ph andp-tolyl) with CrO 3 and of their sodium salts withtrans-[CrCl 2 (H 2 O) 4]Cl2H 2 O in a 3∶1 molar ratio yield three types of oxo/hydroxo bridged complexes: by: 2.
Phosphorus, arsenic and antimony complexes of the main group elements (dimethylarsine) dee bis(diethylphosphino)ethane A- INTRODUCTION Transition metal complexes of phosphorus, arsenic and antimony donors have been extensively studied during the past 20 years [I], The metals of group IA and IIA do not complex with heavy group VB donors Cited by: In coordination chemistry phosphines are L-type ligands.
Unlike most metal ammine complexes, metal phosphine complexes tend to be lipophilic, displaying good solubility in organic solvents.
They also are compatible with metals in multiple oxidation states. Because of these two features, metal phosphine complexes are useful in homogeneous catalysis. Modification of transition-metal complexes by complexation with Lewisbase ligands, especially phosphines or phosphites, has led to major improvements in catalytic reactivity and selectivity.(1,2.
Phosphorus Donor Ligands. Phosphorus, arsenic, antimony, and bismuth ligands have been discussed in CCC ().
Complexes containing bonds between scandium, yttrium, and phosphorus or arsenic have been reviewed, as have complexes with neutral phosphorus ligands.
Many of the complexes described in these reviews contain organic. However, the organoelement compounds of phosphorus, arsenic and antimony find usefulness as ligands in transition metal chemistry due to their σ-donor and π-acceptor abilities which can be readily tuned by simply changing the substituents.
/ in,lrt; nuci Chem. VIII pp 4:tI Pergamon Press. Printed in Great Britain MIXED COMPLEXES OF RUTHENIUM(III) AND RUTHENIUM(II) WITH TRIPHENYLPHOSPHINE OR TRIPHENYLARSINE AND OTHER LIGANDS K. NATARAJAN, RAJ K. PODDAR and UMESH AGARWALA Department of Chemistry, Indian Institute of Technology, Kanpur, U.P., India Cited by: The ligands SbPh 2 Me and SbPhMe 2 form conventional platinum(II) complexes, cis-PtL 2 X 2 (X = Cl, Br.
In addition, the unusual purple five-coordinate complexes PtL 3 I 2 are formed in the solid state. These dissociate in solution by loss of ligand (L = SbPh 2 Me) or of iodide (L = SbPhMe 2).The presumably four-coordinate Pt(Sb Ph Me 2) 4 Cl 2 is also by: The use of tertiary bismutbines as ligands has been mentioned in a book devoted to transition metal complexes of phosphines, arsines, and atibines [4J, and a list of the few organobismuth compounds that were subjected to X-ray analysis in and was published in Volume 4 of Molecular Structures and Dimensions [Cited by: 1.
Studies of phosphorus compounds using the magnetic resonance spectra of nuclei other than phosphorus Progress in Nuclear Magnetic Resonance Spectroscopy1, DOI: /S(66) R.G. Hayter, L.F. Williams. Phosphorus- and arsenic-bridged complexes of metal carbonyls—VIII.
Otto J. Scherer, Complexes with Substituent‐free Acyclic and Cyclic Phosphorus, Arsenic, Antimony, and Bismuth Ligands, Angewandte Chemie International Edition in English, 29, 10, (), ().
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Purchase Annual Reports in Inorganic and General Syntheses - 1st Edition. Print Book & E-Book. ISBNComplexes with Phosphorus and Arsenic Ligands Complexes with Oxygen Linkage Transition Metal Complexes Cationic Complexes Stability References. Edition: 1.The first direct complexation of a stable phosphino carbene to a transition metal center is described.
Both η1- and η2-coordination modes have been characterized spectroscopically. The Fischer-type structure of the η1-carbene rhodium complex was revealed by an X-ray diffraction study.